IDENTIFICATION OF SALT COMPOUNDS IN ATMOSPHERIC AEROSOL BY ITS HYGROSCOPIC AND THERMODYNAMIC CHARACTERISTICS
Abstract and keywords
Abstract:
The characteristics of the condensation activity and volatility of submicron atmospheric aerosol recorded in the air mass arriving in Tomsk from the Vasyugan Marshes and Baraba Steppes in February 2025 were analyzed. A high condensation activity of medium-dispersed particles with radii of 0.2÷1 µm was detected with a high proportion of non-burning residue in the aerosol, which can only be explained by the high content of salt compounds in the particles.

Keywords:
ATMOSPHERIC AEROSOL, HYGROSCOPIC AND THERMODYNAMIC CHARACTERISTICS
References

1. Rozenberg G.V. Rasseyanie sveta v zemnoy atmosfere // UFN. 1960. T. 71. vyp. 2, C. 173–213.

2. Yunge H. Himicheskiy sostav i radiaktivnost' atmosfery // M.: Mir, 1965. 424 C.

3. Rozenberg G.V., Sandomirskiy A.B. Opticheskaya stratifikaciya atmosfernogo aerozolya //Izv. AN SSSR. FAO. 1971. T. 7. № 7. C. 737–749.

4. Bullrich K. Scattering Radiation in the Atmosphere and the Natural Aerosol // Advances in Geophys. 1964 V. 10. P. 99–260.

5. Zuev V.E. Prozrachnost' atmosfery dlya vidimyh i infrakrasnyh luchey // M.: Sov.radio, 1966. 317 S.

6. Rozenberg G.V. Opticheskie issledovaniya atmosfernogo aerozolya // UFN. 1968. T. 95, vyp. 1, S. 159–208.

7. Rozenberg G.V. Svoystva atmosfernogo aerozolya po dannym opticheskogo issledovaniya // Izv. AN SSSR. FAO. 1967. T. 3. № 9, S.936–949.

8. Atmosfernyy aerozol' i ego vliyanie na perenos izlucheniya. // Pod red. Kondrat'eva K.Ya. L.: Gidrometeoizdat, 1978. 119 S.

9. Budyko M.I., Golicyn G.S., Izrael' Yu.A. Global'nye klimaticheskie katastrofy. // M.: Gidrometeoizdat, 1986. 160 S.

10. Rozenberg G.V. Vozniknovenie i razvitie atmosfernogo aerozolya – kineticheski obuslovlennye parametry // Izv. AN SSSR. FAO. 1983. T. 19. № 1. S. 21–35.

11. Zuev V.E., Krekov G.M. Opticheskie modeli atmosfery / L.: Gidrometeoizdat, 1986, 256 s.

12. Penner, J., M. Andreae, H. Annegarn, L. Barrie, J. Feichter, D. Hegg, A. Jayaraman, R. Leaitch, D. Murphy, J. Nganga, G. Pitari . Aerosols, their direct and indirect effects, in Climate Change 2001: Working group I: The Scientific Basis (edited by J. Houghton, Y. Ding, D. Griggs, M. Noguer, P. Linden, X. Dai, K. Maskell, C. Johnson) // Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA. 2001. chap. 5, pp. 289–348.

13. Panchenko M. V., Kozlov V. S., Pol'kin V. V., Terpugova S. A., Tumakov A. G., Shmargunov V. P. Vosstanovlenie opticheskih harakteristik troposfernogo aerozolya Zapadnoy Sibiri na osnove obobschennoy empiricheskoy modeli, uchityvayuschey pogloschayuschie i gigroskopicheskie svoystva chastic // Optika atmosfery i okeana. 2012. T. 25. № 01. S. 46-54.

14. Gorchakov G.I., Emilenko A.S., Isakov A.A., Metreveli D.M., Sviridenkov M.A., Sidorov V.N. The properties of near-ground aerosol. In: Atmospheric optics and aerosol. Moscow: Nauka, 1986. P. 42-64.

15. Gorchakov G.I., Emilenko A.S., Isakov A.A., Sviridenkov M.A., Sidorov V.N. Temporal behavior of optical and microphysical characteristics of the submicron fraction of near-ground aerosol as assessed from the data of AFAEX-79. In: Comprehensive Soviet-American experiment on the study of background aerosol. Leningrad: Gidrometeoizdat, 1986. P. 80-91.

16. Ivlev L.S. Himicheskiy sostav i struktura atmosfernyh aerozoley. L.: Izd-vo LGU. 1982. 368 s.

17. Kondrat'ev K.Ya. Aerozol' kak klimatoobrazuyuschiy komponent atmosfery.1. Fizicheskie svoystva i himicheskiy sostav // Optika atmosfery i okeana. 2002. T. 15. № 2. S. 123-146.

18. An W. J., Pathak R. K., Lee B. H., Pandis S. N. Aerosol Volatility Measurement Using an Improved Thermodenuder: Application to Secondary Organic Aerosol, J. Aerosol Sci., 38, 305– 314, 2007.

19. Faulhaber A. E., Thomas B. M., Jimenez J. L., Jayne J. T., Worsnop D. R., Ziemann P. J. Characterization of a thermodenuder-particle beam mass spectrometer system for the study of organic aerosol volatility and composition, Atmos. Meas. Tech., 2, 15–31, doihttps://doi.org/10.5194/amt-2-15-2009, 2009.

20. Cappa C. D., Wilson K. R. Evolution of organic aerosol mass spectra upon heating: implications for OA phase and partitioning behavior, Atmos. Chem. Phys., 11, 1895–1911, doihttps://doi.org/10.5194/acp- 11-1895-2011, 2011.

21. Saleh R., Shihadeh A., Khlystov A. On transport phenomena and equilibration time scales in thermodenuders, Atmos. Meas. Tech., 4, 571–581, doihttps://doi.org/10.5194/amt-4-571-2011, 2011.

22. Backman J., Virkkula A., Petaja T., Aurela M., Frey A., Hillamo R. Impacts of volatilisation on light scattering and filter-based absorption measurements: a case study, Atmos. Meas. Tech., 3, 1205–1216, doihttps://doi.org/10.5194/amt-3-1205-2010, 2010.

23. Hakkinen S. A. K., Aijala M., Lehtipalo K., Junninen H., Backman J., Virkkula A., Nieminen T. , Vestenius M., Hakola H., Ehn M. , Worsnop D. R., Kulmala M. , Petaja T., Riipinen I. Long-term volatility measurements of submicron atmospheric aerosol in Hyytiala, Finland // Atmos. Chem. Phys., 2012, 12, 10771–10786, doihttps://doi.org/10.5194/acp-12-10771-2012

24. Huffman, J. A., Docherty, K. S., Aiken, A. C., Cubison, M. J., Ulbrich, I. M., DeCarlo, P. F., Sueper, D., Jayne, J. T., Worsnop, D. R., Ziemann, P. J., and Jimenez, J. L.: Chemically-resolved aerosol volatility measurements from two megacity field studies // Atmos. Chem. Phys. 2009, 9, 7161–7182, doihttps://doi.org/10.5194/acp-9-7161-2009.

25. Viktor V. Pol'kin, Mikhail V. Panchenko. Aspects of a technique for investigation of the volatility parameters of species in the composition of atmospheric aerosol in the size range 0.3–5 µm, Proc. SPIE 12780, 29th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, Vol. 12780, 127801Y (17 October 2023); doi:https://doi.org/10.1117/12.2688315.

26. Pol’kin V. V., Panchenko M. V.,. Terpugova S. A. Condensation Activity of Different-Size Particles of Atmospheric Aerosol Using Photoelectric Counter Measurements // Atmospheric and Oceanic Optics, 2022, Vol. 35, No. 2, pp. 133–141. https://doi.org/10.1134/S1024856022020075.

27. Ivlev L.S. Himicheskiy sostav i struktura atmosfernyh aerozoley. L.: Izd-vo LGU. 1982. 368 s.

28. Batcher S., Charlson R. Vvedenie v himiyu atmosfery. M.: Izd-vo «Mir». 1977. 270 s.

29. Pol'kin V.V., Shmargunov V.P., Panchenko M.V. Aprobaciya metodiki i apparatury dlya issledovaniya parametrov kondensacionnoy aktivnosti i letuchesti veschestva v aerozole [Elektronnyy resurs] // V sbornike: Optika atmosfery i okeana. Fizika atmosfery. Sbornik materialov XXX Yubileynogo Mezhdunarodnogo simpoziuma. Sankt-Peterburg, 2024. C.315-329. DOI:https://doi.org/10.56820/OAO30B13

Login or Create
* Forgot password?